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JEE MAIN - Chemistry (2013 (Offline) - No. 1)

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0oC. As it does so, it absorbs 208J of heat. The values of q and w for the process will be :
(R = 8.314 J/mol K) ( l n 7.5 = 2.01)
q = – 208 J, w = – 208 J
q = – 208 J, w = + 208 J
q = + 208 J, w = + 208 J
q = + 208 J, w = – 208 J

توضيح

By Ist law of thermodynamics, q = $$\Delta $$E – W

At const T, ∆E = 0

q = – W

Heat absorbed = 208 J

$$ \therefore $$ q = +208 J

W = – 208 J

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